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| Title: | Di-tert-butylphosphate complexes of Mn(II) and Cu(II) as single-source precursors for metal phosphate materials |
| Authors: | MURUGAVEL, R
SATHIYENDIRAN, M |
| Keywords: | routes
orthosilicate
oxides
model |
| Issue Date: | 2001 |
| Publisher: | CHEMICAL SOC JAPAN |
| Citation: | CHEMISTRY LETTERS, (1), 84-85 |
| Abstract: | Octahedral Mn(II) and Cu(II) di-tert-butylphosphate (L) complexes [ML2(imz)(4)] have been synthesized and characterized using IR, UV-vis, luminescence, and EPR spectroscopy and single crystal X-ray diffraction studies. Thermal decomposition of both the complexes (probed by TGA, DTA, and DSC) indicate stepwise elimination of iso-butene. imidazole and water to finally yield the respective ceramic materials Mn(PO3)(2) or Cu(PO3)(2). |
| URI: | http://dx.doi.org/10.1246/cl.2001.84
http://dspace.library.iitb.ac.in/xmlui/handle/10054/5400
http://hdl.handle.net/10054/5400 |
| ISSN: | 0366-7022 |
| Appears in Collections: | Article
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