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|Title: ||Di-tert-butylphosphate complexes of Mn(II) and Cu(II) as single-source precursors for metal phosphate materials|
|Authors: ||MURUGAVEL, R|
|Issue Date: ||2001|
|Publisher: ||CHEMICAL SOC JAPAN|
|Citation: ||CHEMISTRY LETTERS, (1), 84-85|
|Abstract: ||Octahedral Mn(II) and Cu(II) di-tert-butylphosphate (L) complexes [ML2(imz)(4)] have been synthesized and characterized using IR, UV-vis, luminescence, and EPR spectroscopy and single crystal X-ray diffraction studies. Thermal decomposition of both the complexes (probed by TGA, DTA, and DSC) indicate stepwise elimination of iso-butene. imidazole and water to finally yield the respective ceramic materials Mn(PO3)(2) or Cu(PO3)(2).|
|Appears in Collections:||Article|
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