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| Title: | CRYSTALLIZATION CHARACTERISTICS OF VITROVAC-4040 (FE39NI39MO4SI6B12) |
| Authors: | RAJA, VS RANGANATHAN, S |
| Keywords: | si-b alloys metallic glasses fe kinetics stability behavior fe80b20 |
| Issue Date: | 1991 |
| Publisher: | CARL HANSER VERLAG |
| Citation: | ZEITSCHRIFT FUR METALLKUNDE, 82(12), 907-912 |
| Abstract: | The metallic glass Vitrovac 4040 with the composition Fe39Ni39Mo4Si6B12 crystallizes in the order alpha-Fe, hexagonal Ni5Si2 and gamma-(Fe,Ni,Mo) by primary, secondary and polymorphic modes, respectively. The activation energies determined from the non-isothermal kinetics using Kissinger method turn out to be 490, 550 and 449 kJ.mol-1 for the above crystallization reactions. It has been observed that alpha transforms to gamma during annealing. Further, the bct (Fe1-xNix)3B phase has been identified when the glass is annealed above 1023 K. |
| URI: | http://dspace.library.iitb.ac.in/xmlui/handle/10054/5302 http://hdl.handle.net/10054/5302 |
| ISSN: | 0044-3093 |
| Appears in Collections: | Article
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