Bis(acetylacetonato-kappa O-2,O ')[2,2 '-methylenebis(4,6-xylenolato)-kappa O-2,O ']titanium(IV)

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Title:	Bis(acetylacetonato-kappa O-2,O ')[2,2 '-methylenebis(4,6-xylenolato)-kappa O-2,O ']titanium(IV)
Authors:	BALAKRISHNA, MS PANDA, R MAGUE, JT
Keywords:	polymerization catalysts complexes ligand
Issue Date:	2007
Publisher:	BLACKWELL PUBLISHING
Citation:	ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 63(), M1815-U430
Abstract:	The title compound, [Ti(C5H7O2)(2)(C17H18O2)], was synthesized by the reaction of Ti(acac)(2)Cl-2 (acac = acetylacetonate) with one equivalent of the diol {[HOC6H2(Me)(2)](mu-CH2)[(Me)(2)C6H2OH]} in the presence of sodium acetate. The coordination about the Ti atom is slightly distorted octahedral and the bisphenoxo ligand adopts an 'open book' conformation.
URI:	http://dx.doi.org/10.1107/S1600536807026761 http://dspace.library.iitb.ac.in/xmlui/handle/10054/5160 http://hdl.handle.net/10054/5160
ISSN:	1600-5368
Appears in Collections:	Article

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