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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/5160

Title: Bis(acetylacetonato-kappa O-2,O ')[2,2 '-methylenebis(4,6-xylenolato)-kappa O-2,O ']titanium(IV)
Authors: BALAKRISHNA, MS
PANDA, R
MAGUE, JT
Keywords: polymerization catalysts
complexes
ligand
Issue Date: 2007
Publisher: BLACKWELL PUBLISHING
Citation: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 63(), M1815-U430
Abstract: The title compound, [Ti(C5H7O2)(2)(C17H18O2)], was synthesized by the reaction of Ti(acac)(2)Cl-2 (acac = acetylacetonate) with one equivalent of the diol {[HOC6H2(Me)(2)](mu-CH2)[(Me)(2)C6H2OH]} in the presence of sodium acetate. The coordination about the Ti atom is slightly distorted octahedral and the bisphenoxo ligand adopts an 'open book' conformation.
URI: http://dx.doi.org/10.1107/S1600536807026761
http://dspace.library.iitb.ac.in/xmlui/handle/10054/5160
http://hdl.handle.net/10054/5160
ISSN: 1600-5368
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