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|Title: ||Total Synthesis of (+)-Demethoxycardinalin 3|
|Authors: ||FERNANDES, RA|
|Keywords: ||pictet-spengler cyclization|
|Issue Date: ||2010|
|Publisher: ||AMER CHEMICAL SOC|
|Citation: ||JOURNAL OF ORGANIC CHEMISTRY, 75(20), 7029-7032|
|Abstract: ||The total synthesis of (+)-demethoxycardmalm 3 is described The synthetic strategy features the synthesis of dimerie Fischer carbene and us use in a biduectional Doi/ benzamulation reaction to set the dimerie structure of the cardmalms. The oxa-picict-Spengler reaction was used to construct the pyran rings The synthesis as completed in seven steps and an overall yield of 7%|
|Appears in Collections:||Article|
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