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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/4140

Title: Total Synthesis of (+)-Demethoxycardinalin 3
Authors: FERNANDES, RA
MULAY, SV
Keywords: pictet-spengler cyclization
pyranonaphthoquinone antibiotics
asymmetric dihydroxylation
dermocybe cardinalis
crisamicin-a
micromonospora
(+)-kalafungin
derivatives
annulation
complexes
Issue Date: 2010
Publisher: AMER CHEMICAL SOC
Citation: JOURNAL OF ORGANIC CHEMISTRY, 75(20), 7029-7032
Abstract: The total synthesis of (+)-demethoxycardmalm 3 is described The synthetic strategy features the synthesis of dimerie Fischer carbene and us use in a biduectional Doi/ benzamulation reaction to set the dimerie structure of the cardmalms. The oxa-picict-Spengler reaction was used to construct the pyran rings The synthesis as completed in seven steps and an overall yield of 7%
URI: http://dx.doi.org/10.1021/jo101628m
http://dspace.library.iitb.ac.in/xmlui/handle/10054/4140
http://hdl.handle.net/10054/4140
ISSN: 0022-3263
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