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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/4119

Title: Tetranuclear rhodium(I) macrocycle containing cyclodiphosphazane [Rh-2(mu-Cl)(2)(CO)(2){((BuNP)-Bu-t(OC6H4OMe-o))(2)-kappa P](2) and its reversible conversion into trans-[Rh(CO)Cl{((BuNP)-Bu-t(OC6H4OMe-o))(2-)kappa P}(2)]
Authors: CHANDRASEKARAN, P
MAGUE, JT
BALAKRISHNA, MS
Keywords: x-ray structures
complexes
metallomacrocycles
platinum(ii)
diphosphazanes
palladium(ii)
derivatives
ligands
pd(ii)
Issue Date: 2005
Publisher: AMER CHEMICAL SOC
Citation: ORGANOMETALLICS, 24(15), 3780-3783
Abstract: The 1:1 reaction between cis-[(BuNP)-Bu-t(OC6H4OMe-o)](2) (2) and [Rh(mu-Cl)(CO)(2)](2) affords novel tetranuclear rhodium(l) macrocycle (3) containing two cyclodiphosphazanes bridged by two [Rh(mu-Cl)(CO)](2) moieties, whereas the corresponding 4:1 reaction affords trans-[Rh(CO)Cl-{((BuNP)-Bu-t(OC6H4OMe-o))(2)-kappa P}2] (4).
URI: http://dx.doi.org/10.1021/om0502537
http://dspace.library.iitb.ac.in/xmlui/handle/10054/4119
http://hdl.handle.net/10054/4119
ISSN: 0276-7333
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