Tetranuclear rhodium(I) macrocycle containing cyclodiphosphazane [Rh-2(mu-Cl)(2)(CO)(2){((BuNP)-Bu-t(OC6H4OMe-o))(2)-kappa P](2) and its reversible conversion into trans-[Rh(CO)Cl{((BuNP)-Bu-t(OC6H4OMe-o))(2-)kappa P}(2)]

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Title:	Tetranuclear rhodium(I) macrocycle containing cyclodiphosphazane [Rh-2(mu-Cl)(2)(CO)(2){((BuNP)-Bu-t(OC6H4OMe-o))(2)-kappa P](2) and its reversible conversion into trans-[Rh(CO)Cl{((BuNP)-Bu-t(OC6H4OMe-o))(2-)kappa P}(2)]
Authors:	CHANDRASEKARAN, P MAGUE, JT BALAKRISHNA, MS
Keywords:	x-ray structures complexes metallomacrocycles platinum(ii) diphosphazanes palladium(ii) derivatives ligands pd(ii)
Issue Date:	2005
Publisher:	AMER CHEMICAL SOC
Citation:	ORGANOMETALLICS, 24(15), 3780-3783
Abstract:	The 1:1 reaction between cis-[(BuNP)-Bu-t(OC6H4OMe-o)](2) (2) and [Rh(mu-Cl)(CO)(2)](2) affords novel tetranuclear rhodium(l) macrocycle (3) containing two cyclodiphosphazanes bridged by two [Rh(mu-Cl)(CO)](2) moieties, whereas the corresponding 4:1 reaction affords trans-[Rh(CO)Cl-{((BuNP)-Bu-t(OC6H4OMe-o))(2)-kappa P}2] (4).
URI:	http://dx.doi.org/10.1021/om0502537 http://dspace.library.iitb.ac.in/xmlui/handle/10054/4119 http://hdl.handle.net/10054/4119
ISSN:	0276-7333
Appears in Collections:	Article

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