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|Title: ||Structure of the phenylacetylene - Water complex as revealed by infrared-ultraviolet double resonance spectroscopy|
|Authors: ||SINGH, PC|
|Keywords: ||vibrational spectroscopy|
|Issue Date: ||2008|
|Publisher: ||AMER CHEMICAL SOC|
|Citation: ||JOURNAL OF PHYSICAL CHEMISTRY A, 112(15), 3360-3363|
|Abstract: ||The structure of the phenylacetylene-water complex has been elucidated based on spectral shifts in electronic and vibrational transitions. Phenylacetylene forms a cyclic complex with water incorporating C-H center dot center dot center dot O and O-H center dot center dot center dot pi hydrogen bonds, which is different from both the benzene-water and acetylene-water complexes, even though phenylacetylene combines the features of both benzene and acetylene. Formation of such a complex can be rationalized on the basis of cooperativity between the two sets of hydrogen bonds.|
|Appears in Collections:||Article|
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