DSpace
 

DSpace at IIT Bombay >
IITB Publications >
Article >

Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/4018

Title: Proton affinities of borane-amines: Consequences on dihydrogen bonding
Authors: PATWARI, GN
Keywords: main-group elements
hydrogen-bonds
gas-phase
neutron-diffraction
complex
phenol
clusters
spectroscopy
energies
bh3nh3
Issue Date: 2005
Publisher: AMER CHEMICAL SOC
Citation: JOURNAL OF PHYSICAL CHEMISTRY A, 109(10), 2035-2038
Abstract: The calculated proton affinities of four borane-amines using Gaussian-2 theory have been found to be comparable to conventional bases such as water, methanol, and ammonia. On the other hand the structure of protonated borane-ammonia, [HBH3-NH3](+), is found to be drastically different from that of protonated ammonia, [HNH3](+), and can appropriately be described as a eta(2)-H-2 complex with [BH2-NH3](+) molecular cation. Further, the proton affinities of borane-amines are related to the ease of H-2 elimination.
URI: http://dx.doi.org/10.1021/jp044445b
http://dspace.library.iitb.ac.in/xmlui/handle/10054/4018
http://hdl.handle.net/10054/4018
ISSN: 1089-5639
Appears in Collections:Article

Files in This Item:

There are no files associated with this item.

View Statistics

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

 

Valid XHTML 1.0! DSpace Software Copyright © 2002-2010  Duraspace - Feedback