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|Title: ||Infrared-optical double-resonance measurements on O-H center dot center dot center dot H-Ge dihydrogen-bonded phenol-triethylgermanium hydride complex in the gas phase|
|Authors: ||SINGH, PC|
|Keywords: ||main-group elements|
|Issue Date: ||2008|
|Publisher: ||AMER CHEMICAL SOC|
|Citation: ||JOURNAL OF PHYSICAL CHEMISTRY A, 112(26), 5930-5934|
|Abstract: ||Spectroscopic investigation of a dihydrogen-bonded complex between phenol and triethylgermanium hydride is reported here. Laser-induced fluorescence excitation, fluorescence-detected infrared, and IR-UV hole-burning spectroscopic studies were carried out in supersonic jet to investigate the complex formation between phenol and triethylgermanium hydride. The lowering of the O-H stretching frequency of the phenol moiety in the complex with triethylgermanium hydride clearly establishes the role of phenol as hydrogen bond donor. The experimental results together with the ab-initio calculations unambiguously confirm formation of an O-H center dot center dot center dot H-Ge dihydrogen-bonded complex between phenol and triethylgermanium hydride.|
|Appears in Collections:||Article|
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