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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/3906

Title: Infrared-optical double-resonance measurements on O-H center dot center dot center dot H-Ge dihydrogen-bonded phenol-triethylgermanium hydride complex in the gas phase
Authors: SINGH, PC
MAITY, DK
PATWARI, GN
Keywords: main-group elements
unconventional hydrogen-bonds
borane-dimethylamine complex
ammonia-borane
thermal-decomposition
neutron-diffraction
low-temperature
storage
dehydrogenation
bh3nh3
Issue Date: 2008
Publisher: AMER CHEMICAL SOC
Citation: JOURNAL OF PHYSICAL CHEMISTRY A, 112(26), 5930-5934
Abstract: Spectroscopic investigation of a dihydrogen-bonded complex between phenol and triethylgermanium hydride is reported here. Laser-induced fluorescence excitation, fluorescence-detected infrared, and IR-UV hole-burning spectroscopic studies were carried out in supersonic jet to investigate the complex formation between phenol and triethylgermanium hydride. The lowering of the O-H stretching frequency of the phenol moiety in the complex with triethylgermanium hydride clearly establishes the role of phenol as hydrogen bond donor. The experimental results together with the ab-initio calculations unambiguously confirm formation of an O-H center dot center dot center dot H-Ge dihydrogen-bonded complex between phenol and triethylgermanium hydride.
URI: http://dx.doi.org/10.1021/jp801035u
http://dspace.library.iitb.ac.in/xmlui/handle/10054/3906
http://hdl.handle.net/10054/3906
ISSN: 1089-5639
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