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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/3771

Title: Contrasting behavior of bis[2-(4,4-dimethyl-2-oxazolinyl)phenyl] chalcogenides (Se/Te) toward mercuric chloride: Facile cleavage of the Te-C bond
Authors: APTE, SD
ZADE, SS
SINGH, HB
BUTCHER, RJ
Keywords: macrocyclic schiff-base
molecular-structure
asymmetric methoxyselenenylation
organic tellurides
crystal-structures
complexes
chemistry
halides
bromide
diselenides
Issue Date: 2003
Publisher: AMER CHEMICAL SOC
Citation: ORGANOMETALLICS, 22(26), 5473-5477
Abstract: The reactions of R2Se (3) and R2Te (4) (R = 2-(4,4-dimethyl-2-oxazolinyl)phenyl) with HgCl2 and Pd(COD)Cl-2 are described. The reaction of selenoether 3 with HgCl2 affords the expected complex R2SeHgCl2 (5), which is stable in solution. In contrast, the analogous tellurium complex R2TeHgCl2 (6) undergoes slow dismutation in chlorinated solvents to give the fragments RTeCl (7) and RHgCl (8).
URI: http://dx.doi.org/10.1021/om034222s
http://dspace.library.iitb.ac.in/xmlui/handle/10054/3771
http://hdl.handle.net/10054/3771
ISSN: 0276-7333
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