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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/3718

Title: An unusual cyclopentaannulation reaction: Thermolysis of an alpha,beta-unsaturated Fischer carbene complex anchored on a Fe-2(CO)(6)(mu-Se)(2) core
Authors: MATHUR, P
GHOSH, S
SARKAR, A
RHEINGOLD, AL
GUZEI, IA
Keywords: acetylenic bond reduction
selenium complexes
crystal-structure
fe2(co)6(mu-se2)
insertion
Issue Date: 1998
Publisher: AMER CHEMICAL SOC
Citation: ORGANOMETALLICS, 17(4), 770-772
Abstract: An unusual annulation of-a Fischer carbene complex anchored on a Fe-2(CO)(6)(mu-Se)(2) core is examined. Thermolysis of Fe-2(CO)(6){mu-SeC(Ph)=C(Se)[(OEt)C=Cr(CO)(5)]} in THF yields an unusual annulated product, [Fe-2(CO)(6)Se-2{mu-(CO)(3)Cr(eta(5)-C5H(CH2Ph)(Ph)(OEt))}] (1), as characterized by IR and H-1, C-13, and Se-77 NMR spectroscopies, and its structure has been established by single-crystal X-ray diffraction.
URI: http://dx.doi.org/10.1021/om9708182
http://dspace.library.iitb.ac.in/xmlui/handle/10054/3718
http://hdl.handle.net/10054/3718
ISSN: 0276-7333
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