A highly selective, heterogeneous route to enones from allylic and benzylic compounds over mesoporous CrMCM-41 molecular sieves

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Title:	A highly selective, heterogeneous route to enones from allylic and benzylic compounds over mesoporous CrMCM-41 molecular sieves
Authors:	MOHAPATRA, SK SELVAM, P
Keywords:	catalyzed oxidations liquid-phase alkylaromatics (cr)mcm-41 complex
Issue Date:	2007
Publisher:	ACADEMIC PRESS INC ELSEVIER SCIENCE
Citation:	JOURNAL OF CATALYSIS, 249(2), 394-396
Abstract:	A unique combination of oxidant, solvent, and catalyst is proposed for the allylic and benzylic oxidation of alkenes to enones with 100% selectivity and good conversion. The proposed catalyst, CrMCM-41, in combination with H2O2 is found to be highly active and selective for this purpose. The catalyst is also found to be very useful for selective oxidation of toluene and aniline. It is also proved that the catalyst can be reused several times while maintaining its structural integrity and activity. (c) 2007
URI:	http://dx.doi.org/10.1016/j.jcat.2007.04.017 http://dspace.library.iitb.ac.in/xmlui/handle/10054/3340 http://hdl.handle.net/10054/3340
ISSN:	0021-9517
Appears in Collections:	Article

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