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|Title:||Synthesis of C-3-symmetric nano-sized Polyaromatic compounds by trimerization and Suzuki-Miyaura cross-coupling reactions|
|Keywords:||Organic Electroluminescent Devices|
|Publisher:||WILEY-V C H VERLAG GMBH|
|Citation:||EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, (19), 4003-4013|
|Abstract:||Various C-3-symmetric molecules were prepared by trimerization of acetyl aromatic compounds and subsequently coupled with various boronic acids under Pd-0 catalysis conditions to generate oligoaryl/-heteroaryl C-3-symmetric molecules. Several furan- and thiophene-containing star-shaped molecules were prepared by the use of Suzuki-Miyaura cross-coupling as a key step. Structural and conformational details were explored by semi-empirical molecular orbital theory using the AM1 method.|
|Appears in Collections:||Article|
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