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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/12827

Title: Four-, five- and six-coordinated Zn-II complexes of OH-containing ligands: Syntheses, structure and reactivity
Authors: DEY, M
RAO, CP
SAARENKETO, P
RISSANEN, K
KOLEHMAINEN, E
Keywords: carbonic-anhydrase
crystal-structures
vanadium(v) complexes
zinc enzymes
model
derivatives
recognition
ion
monooxovanadium(v)
electrochemistry
Issue Date: 2002
Publisher: WILEY-V C H VERLAG GMBH
Citation: EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, (8), 2207-2215
Abstract: Four-, five- and six-coordinated complexes of Zn-II with OH-rich molecules possessing an ONO binding core were synthesized, characterized and their structures were established by single-crystal X-ray diffraction, The corresponding metal ion geometries were found to be distorted tetrahedral, square pyramidal and octahedral, respectively. The complexes exhibit interesting lattice structures such as layered and corrugated sheets owing to the presence of a number of weak intermolecular interactions. The five-coordinated, water-bound Zn-II complex was studied because of its putative hydrolysis property towards p-nitrophenyl acetate. (C) Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002.
URI: http://dspace.library.iitb.ac.in/xmlui/handle/10054/12827
http://hdl.handle.net/10054/12827
ISSN: 1434-1948
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