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|Title: ||Cross-enyne and ring-closing metathesis cascade: A building-block approach suitable for diversity-oriented synthesis of densely functionalized macroheterocycles with amino acid scaffolds|
|Authors: ||KOTHA, S|
|Issue Date: ||2007|
|Publisher: ||WILEY-V C H VERLAG GMBH|
|Citation: ||EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, (35), 5909-5916|
|Abstract: ||Suitably functionalized glycine derivatives undergo a cross-enyne and ring-closing metathesis cascade to generate macroheterocyclic ring systems in good yield. These macrocycles, prepared on the basis of a fragment coupling strategy, consist of 13-16-membered rings. To this end, 1,5-hexadiene was found to be a promising cross-coupling partner to generate macrocycles by this tandem metathesis sequence. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)|
|Appears in Collections:||Article|
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