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|Title: ||Constrained phenylalanine derivatives by enyne metathesis and Diels-Alder reaction|
|Authors: ||KOTHA, S|
|Keywords: ||amino-acid derivatives|
|Issue Date: ||2001|
|Publisher: ||WILEY-V C H VERLAG GMBH|
|Citation: ||EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, (4), 787-792|
|Abstract: ||A conceptually new approach for the synthesis of indane-based alpha -amino acid derivatives is reported. In this regard, the synthesis of five-membered exocyclic and five-membered inner-outer ring diene building blocks (7 and 15) containing alpha -amino acid moieties is described. Diene 15 is prepared by an enyne metathesis reaction as a key step. In this paper, a full account of our work regarding the Diels-Alder reaction of these dienes with various dienophiles, and the subsequent oxidation of the cycloadducts to give various indane-based alpha -amino acid derivatives is reported.|
|Appears in Collections:||Article|
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