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| Title: | 2-(Dimethylaminomethyl)phenyl phenyl telluride |
| Authors: | CHAKRABORTY, T
SINGH, HB
BUTCHER, RJ |
| Keywords: | cross-coupling reactions
vinylic tellurides
organic tellurides
crystal
n,n-dimethylbenzylamine
chloride
radii |
| Issue Date: | 2009 |
| Publisher: | WILEY-BLACKWELL PUBLISHING, INC |
| Citation: | ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 65(), O2562-+ |
| Abstract: | The title compound, C(15)H(17)NTe, is a heteroleptic Te, N-bidentate ligand having a short Te center dot center dot center dot N contact [2.8079 (16) angstrom] involving a secondary bonding interaction between the amino N and Te(II) atoms. The Te-C bond [2.136 (2) angstrom] trans to the amino group is slightly elongated compared to the other Te-C bond [2.1242 (18) angstrom] due to the hypervalent interaction. The bond angle for the trans N-Te-C atoms [164.92 (6)degrees] deviates significantly from linearity. |
| URI: | http://dx.doi.org/10.1107/S1600536809038161
http://dspace.library.iitb.ac.in/xmlui/handle/10054/12759
http://hdl.handle.net/10054/12759 |
| ISSN: | 1600-5368 |
| Appears in Collections: | Article
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