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|Title: ||2-(Dimethylaminomethyl)phenyl phenyl telluride|
|Authors: ||CHAKRABORTY, T|
|Keywords: ||cross-coupling reactions|
|Issue Date: ||2009|
|Publisher: ||WILEY-BLACKWELL PUBLISHING, INC|
|Citation: ||ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 65(), O2562-+|
|Abstract: ||The title compound, C(15)H(17)NTe, is a heteroleptic Te, N-bidentate ligand having a short Te center dot center dot center dot N contact [2.8079 (16) angstrom] involving a secondary bonding interaction between the amino N and Te(II) atoms. The Te-C bond [2.136 (2) angstrom] trans to the amino group is slightly elongated compared to the other Te-C bond [2.1242 (18) angstrom] due to the hypervalent interaction. The bond angle for the trans N-Te-C atoms [164.92 (6)degrees] deviates significantly from linearity.|
|Appears in Collections:||Article|
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