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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/11870

Title: TRANSITION-METAL SACCHARIDE CHEMISTRY AND BIOLOGY - SYNTHESIS, CHARACTERIZATION, REDOX BEHAVIOR, BIOINTERACTION AND DATA CORRELATIONS OF DINUCLEAR CHROMIUM(III) COMPLEXES
Authors: KAIWAR, SP
RAGHAVAN, MSS
RAO, CP
Keywords: sugar-type ligands
d-fructose
d-glucose
iron(iii) complexes
potassium chromate
amino-acid
ions
coordination
derivatives
oxidation
Issue Date: 1995
Publisher: ROYAL SOC CHEMISTRY
Citation: JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (10), 1569-1576
Abstract: A series of dinuclear chromium(III) complexes has been synthesised by reduction of chromate by a variety of saccharides and related compounds. The complexes have been characterised by various analytical (elemental and ICP-AES analysis, TLC, HPLC) and spectroscopic (UV/VIS, FTIR, EPR, H-1 and C-13 NMR) methods. Antiferromagnetic interactions between the two Cr-III centres have been established by magnetic susceptibility measurements and the hydrolytic stability and redox behaviour of the complexes have been established by extensive electrochemical studies which gave several correlations. The interaction of some of the complexes with DNA has been studied by gel electrophoresis.
URI: http://dx.doi.org/10.1039/dt9950001569
http://dspace.library.iitb.ac.in/xmlui/handle/10054/11870
http://hdl.handle.net/10054/11870
ISSN: 0300-9246
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