Synthesis and single crystal X-ray structure of the first cationic Pd(II) complex of a tellurium-containing polyaza macrocycle: contrasting reactions of Pd(II) and Pt(II) with a 22-membered macrocyclic Schiff base

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Title:	Synthesis and single crystal X-ray structure of the first cationic Pd(II) complex of a tellurium-containing polyaza macrocycle: contrasting reactions of Pd(II) and Pt(II) with a 22-membered macrocyclic Schiff base
Authors:	MENON, SC PANDA, A SINGH, HB BUTCHER, RJ
Keywords:	selenium coronands donor atoms palladium(ii) reactivity chemistry 2-(2'-pyridyl)phenyl(para-ethoxyphenyl)tellurium(ii) behavior nitrogen m=pd
Issue Date:	2000
Publisher:	ROYAL SOC CHEMISTRY
Citation:	CHEMICAL COMMUNICATIONS, (2), 143-144
Abstract:	The reaction of the tellurium containing macrocyclic Schiff base 1 with Pd(PhCN)(2)Cl-2 and NH4PF6 gives the expected cationic complex [Pd(II)1][PF6](2); by contrast the reaction of 1 with Pt(cod)Cl-2 proceeds via novel transmetallation to yield an organoplatinum complex.
URI:	http://dx.doi.org/10.1039/a908683h http://dspace.library.iitb.ac.in/xmlui/handle/10054/11837 http://hdl.handle.net/10054/11837
ISSN:	1359-7345
Appears in Collections:	Article

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