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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/11806

Title: Seeking tetrameric transition metal phosphonate with a D4R core and organising it into a 3-D supramolecular assembly
Authors: MURUGAVEL, R
SHANMUGAN, S
Keywords: pyrazole ligands
tetranuclear
aluminophosphonate
transformations
phosphates
elements
cluster
cages
units
Issue Date: 2007
Publisher: ROYAL SOC CHEMISTRY
Citation: CHEMICAL COMMUNICATIONS, (12), 1257-1259
Abstract: The first cubic zinc phosphonate [tBuPO(3)Zn(2-apy)] 4 (1) whose core resembles the D4R SBU of zeolites, has been synthesised from a reaction between zinc acetate, tert- butylphosphonic acid and 2- aminopyridine at room temperature; the X- ray structure determination reveals that the molecules of 1, which crystallise in the tetragonal I4(1)/a space group with crystallographically imposed 4 symmetry, form a 3-D supramolecular assembly aided by N-(HO)-O-... hydrogen bonding.
URI: http://dx.doi.org/10.1039/b616439k
http://dspace.library.iitb.ac.in/xmlui/handle/10054/11806
http://hdl.handle.net/10054/11806
ISSN: 1359-7345
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