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|Title: ||Seeking tetrameric transition metal phosphonate with a D4R core and organising it into a 3-D supramolecular assembly|
|Authors: ||MURUGAVEL, R|
|Keywords: ||pyrazole ligands|
|Issue Date: ||2007|
|Publisher: ||ROYAL SOC CHEMISTRY|
|Citation: ||CHEMICAL COMMUNICATIONS, (12), 1257-1259|
|Abstract: ||The first cubic zinc phosphonate [tBuPO(3)Zn(2-apy)] 4 (1) whose core resembles the D4R SBU of zeolites, has been synthesised from a reaction between zinc acetate, tert- butylphosphonic acid and 2- aminopyridine at room temperature; the X- ray structure determination reveals that the molecules of 1, which crystallise in the tetragonal I4(1)/a space group with crystallographically imposed 4 symmetry, form a 3-D supramolecular assembly aided by N-(HO)-O-... hydrogen bonding.|
|Appears in Collections:||Article|
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