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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/11789

Title: Reactivity of cis-bis(acetylacetonato)dichlorotitanium(IV) towards hydroxy-containing ligands: isolation and characterisation of products
Authors: RAO, PV
RAO, CP
WEGELIUS, EK
KOLEHMAINEN, E
RISSANEN, K
Keywords: vanadium(v) complexes
molecular-structure
carboxylic-acids
derivatives
salicylaldehyde
crystal
base
monooxovanadium(v)
electrochemistry
spectroscopy
Issue Date: 1999
Publisher: ROYAL SOC CHEMISTRY
Citation: JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (24), 4469-4474
Abstract: The reactivity of cis-[Ti(acac)(2)Cl-2] with a number of OH containing ligands has been explored. Corresponding products have been synthesized, isolated and characterised. Three dimensional structures of some of the products were established by single crystal X-ray diffraction. The reactivity of these ligands towards non-oxo titanium centres has been found to be different from that of oxometal centres of V-V, Mo-VI and U-VI. All the products of Ti-IV isolated were mononuclear complexes possessing one or two ligands. Both the molecular and crystal structures of the titanium products are found to be different from those of the oxometal ones.
URI: http://dx.doi.org/10.1039/a906985b
http://dspace.library.iitb.ac.in/xmlui/handle/10054/11789
http://hdl.handle.net/10054/11789
ISSN: 0300-9246
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