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|Title:||Reactivity of cis-bis(acetylacetonato)dichlorotitanium(IV) towards hydroxy-containing ligands: isolation and characterisation of products|
|Publisher:||ROYAL SOC CHEMISTRY|
|Citation:||JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (24), 4469-4474|
|Abstract:||The reactivity of cis-[Ti(acac)(2)Cl-2] with a number of OH containing ligands has been explored. Corresponding products have been synthesized, isolated and characterised. Three dimensional structures of some of the products were established by single crystal X-ray diffraction. The reactivity of these ligands towards non-oxo titanium centres has been found to be different from that of oxometal centres of V-V, Mo-VI and U-VI. All the products of Ti-IV isolated were mononuclear complexes possessing one or two ligands. Both the molecular and crystal structures of the titanium products are found to be different from those of the oxometal ones.|
|Appears in Collections:||Article|
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