O-H Bond elongation in co-ordinated water through intramolecular P = O center dot center dot center dot H-O bonding. 'Snap-shots' in phosphate ester hydrolysis

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Title:	O-H Bond elongation in co-ordinated water through intramolecular P = O center dot center dot center dot H-O bonding. 'Snap-shots' in phosphate ester hydrolysis
Authors:	MURUGAVEL, R SATHIYENDIRAN, M POTHIRAJA, R BUTCHER, RJ
Keywords:	tert-butyl phosphate molecular recognition crystal-structure precursors complexes receptors diesters ligands cages site
Issue Date:	2003
Publisher:	ROYAL SOC CHEMISTRY
Citation:	CHEMICAL COMMUNICATIONS, (20), 2546-2547
Abstract:	Molecular structure of [Cu(dtbp)(2)(phen)(OH2)] (dtbp- H = di-tert-butylphosphate, phen = 1,10-phenanthroline), determined at 293, 203 and 93 K, provides useful snap-shots of O-H bond activation of a metal-bound water, which is aided by an intramolecular P=O...H-O hydrogen bonding interaction.
URI:	http://dx.doi.org/10.1039/b306038a http://dspace.library.iitb.ac.in/xmlui/handle/10054/11768 http://hdl.handle.net/10054/11768
ISSN:	1359-7345
Appears in Collections:	Article

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