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|Title: ||O-H Bond elongation in co-ordinated water through intramolecular P = O center dot center dot center dot H-O bonding. 'Snap-shots' in phosphate ester hydrolysis|
|Authors: ||MURUGAVEL, R|
|Keywords: ||tert-butyl phosphate|
|Issue Date: ||2003|
|Publisher: ||ROYAL SOC CHEMISTRY|
|Citation: ||CHEMICAL COMMUNICATIONS, (20), 2546-2547|
|Abstract: ||Molecular structure of [Cu(dtbp)(2)(phen)(OH2)] (dtbp- H = di-tert-butylphosphate, phen = 1,10-phenanthroline), determined at 293, 203 and 93 K, provides useful snap-shots of O-H bond activation of a metal-bound water, which is aided by an intramolecular P=O...H-O hydrogen bonding interaction.|
|Appears in Collections:||Article|
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