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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/11768

Title: O-H Bond elongation in co-ordinated water through intramolecular P = O center dot center dot center dot H-O bonding. 'Snap-shots' in phosphate ester hydrolysis
Authors: MURUGAVEL, R
SATHIYENDIRAN, M
POTHIRAJA, R
BUTCHER, RJ
Keywords: tert-butyl phosphate
molecular recognition
crystal-structure
precursors
complexes
receptors
diesters
ligands
cages
site
Issue Date: 2003
Publisher: ROYAL SOC CHEMISTRY
Citation: CHEMICAL COMMUNICATIONS, (20), 2546-2547
Abstract: Molecular structure of [Cu(dtbp)(2)(phen)(OH2)] (dtbp- H = di-tert-butylphosphate, phen = 1,10-phenanthroline), determined at 293, 203 and 93 K, provides useful snap-shots of O-H bond activation of a metal-bound water, which is aided by an intramolecular P=O...H-O hydrogen bonding interaction.
URI: http://dx.doi.org/10.1039/b306038a
http://dspace.library.iitb.ac.in/xmlui/handle/10054/11768
http://hdl.handle.net/10054/11768
ISSN: 1359-7345
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