Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/xmlui/handle/10054/11754
Title: N-Glycosylamines of 4,6-O-ethylidene-alpha-D-glucopyranose: synthesis, characterisation and structure of CO2H, Cl and F ortho-substituted phenyl derivatives and metal ion complexes of the CO2H derivative
Authors: SAH, AK
RAO, CP
SAARENKETO, PK
WEGELIUS, EK
RISSANEN, K
KOLEHMAINEN, E
Keywords: Titanium-Carbohydrate Complexes
Enantioselective Syntheses
Nickel(Ii) Complexes
Glycoside Ligands
Crown-Ether
Coordination
Diacetoneglucose
Platinum(Iv)
Chemistry
Sugars
Issue Date: 2000
Publisher: ROYAL SOC CHEMISTRY
Citation: JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (20), 3681-3687
Abstract: A saccharide based ligand suitable for metal binding (HLCOOH) has been synthesized using 4,6-O-ethylidene-alpha-D-glucopyranose (4,6-O-EGP) and anthranilic acid. A few analogous glycosylamines with chloro and fluoro ortho substitutions have also been synthesized and characterised. Complexes of HLCOOH with Na+, K+, Mg2+, Ca2+, Ba2+, Cd2+ and Hg2+ have been isolated and characterised fully. The crystal structures of 4,6-O-EGP, the chloro analogue of HLCOOH and the K+ complex of L-COOH are established. The anomeric nature, orientation of the binding core and the co-ordination aspects of K+ have been derived from these structures.
URI: http://dx.doi.org/10.1039/b004854m
http://dspace.library.iitb.ac.in/xmlui/handle/10054/11754
http://hdl.handle.net/10054/11754
ISSN: 1470-479X
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