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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/11740

Title: Isolation and reactivity of an unusually stable organoselenenyl azide
Authors: SRIVASTAVA, K
CHAKRABORTY, T
SINGH, HB
SINGH, UP
BUTCHER, RJ
Keywords: crystal-structure
nmr-spectroscopy
organotellurium compounds
organochalcogen se
terminal alkynes
te compounds
n,n-dimethylbenzylamine
stabilization
pseudohalides
coordination
Issue Date: 2010
Publisher: ROYAL SOC CHEMISTRY
Citation: DALTON TRANSACTIONS, 39(42), 10137-10141
Abstract: The stabilities of a series of isolated covalent selenium(II) azides such as [2-[1-(3,5-dimethylphenyl)- 2-naphthyl]-4,5-dihydro-4,4-dimethyloxazole] selenium azide (2a), [2-(4,4-dimethyl-2-oxazolinyl) phenyl]selenenyl azide (3a), [o-(2,6-diisopropylphenyl-iminomethinyl) phenyl] selenenyl azide (4a), [o-(R)-(methylbenzyliminomethinyl) phenyl] selenenyl azide (5a) and o-formylphenylselenenyl azide (6a) are rationalized; also the reactivity of first room temperature stable azide (2a) toward 1,3-cycloaddition has been explored.
URI: http://dx.doi.org/10.1039/c0dt00509f
http://dspace.library.iitb.ac.in/xmlui/handle/10054/11740
http://hdl.handle.net/10054/11740
ISSN: 1477-9226
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