Contrasting coordination behaviour of 22-membered chalcogenaaza (Se, Te) macrocycles towards Pd(II) and Pt(II): Isolation and structural characterization of the first metallamacrocyle with a C-Pt-Se linkage

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Title:	Contrasting coordination behaviour of 22-membered chalcogenaaza (Se, Te) macrocycles towards Pd(II) and Pt(II): Isolation and structural characterization of the first metallamacrocyle with a C-Pt-Se linkage
Authors:	PANDA, S SINGHA, HB BUTCHER, RJ
Keywords:	x-ray-structure crystal-structure schiff-base complexes tellurium chemistry platinum(ii) selenoether ligands palladium(ii)
Issue Date:	2004
Publisher:	ROYAL SOC CHEMISTRY
Citation:	CHEMICAL COMMUNICATIONS, (3), 322-323
Abstract:	Interaction of the 22-membered selenaaza macrocyle 3 with Pt(II) leads to the formation of the novel cationic Pt(IV) metallamacrocylic complex 5 via the oxidative addition of a C-Se bond to Pt(II), whereas corresponding reactions of 3 and 4 with Pd(II) afford cationic complexes 6 and 7 with differing ligating properties.
URI:	http://dx.doi.org/10.1039/b312358h http://dspace.library.iitb.ac.in/xmlui/handle/10054/11700 http://hdl.handle.net/10054/11700
ISSN:	1359-7345
Appears in Collections:	Article

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