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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/11700

Title: Contrasting coordination behaviour of 22-membered chalcogenaaza (Se, Te) macrocycles towards Pd(II) and Pt(II): Isolation and structural characterization of the first metallamacrocyle with a C-Pt-Se linkage
Authors: PANDA, S
SINGHA, HB
BUTCHER, RJ
Keywords: x-ray-structure
crystal-structure
schiff-base
complexes
tellurium
chemistry
platinum(ii)
selenoether
ligands
palladium(ii)
Issue Date: 2004
Publisher: ROYAL SOC CHEMISTRY
Citation: CHEMICAL COMMUNICATIONS, (3), 322-323
Abstract: Interaction of the 22-membered selenaaza macrocyle 3 with Pt(II) leads to the formation of the novel cationic Pt(IV) metallamacrocylic complex 5 via the oxidative addition of a C-Se bond to Pt(II), whereas corresponding reactions of 3 and 4 with Pd(II) afford cationic complexes 6 and 7 with differing ligating properties.
URI: http://dx.doi.org/10.1039/b312358h
http://dspace.library.iitb.ac.in/xmlui/handle/10054/11700
http://hdl.handle.net/10054/11700
ISSN: 1359-7345
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