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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/11628

Title: TRANSITION-METAL SACCHARIDE CHEMISTRY - D-GLUCOSE COMPLEXES OF MN(II), CO(II), NI(II), CU(II) AND ZN(II)
Authors: BANDWAR, RP
RAGHAVAN, MSS
RAO, CP
Keywords: potassium chromate
d-fructose
ions
cations
coordination
reduction
Issue Date: 1995
Publisher: RAPID SCIENCE PUBLISHERS
Citation: BIOMETALS, 8(1), 19-24
Abstract: Metal complexes of D-glucose (D-Glc) from large cation containing dibromo-dichloro salts of dipositive metals [NEt(4)](2)[MBr(2)Cl(2)] (M = Mn, Co, Ni, Cu and Zn) and the disodium salt of glucose were synthesized from a MeOH:MeCN mixture. The complexes were characterized by UV-vis absorption, circular dichroism, IR and proton magnetic resonance spectroscopies, and by elemental analysis, and were found to be Na[M(D-Glc)(OMe)Cl]. Cyclic voltammetric studies of these complexes, in the acidic to neutral pH range, indicated no dissociation, even in highly acidic conditions.
URI: http://dspace.library.iitb.ac.in/xmlui/handle/10054/11628
http://hdl.handle.net/10054/11628
ISSN: 0966-0844
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