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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/11503

Title: TRANSITION-METAL SACCHARIDE CHEMISTRY - SYNTHESIS, SPECTROSCOPY, ELECTROCHEMISTRY AND MAGNETIC STUDIES OF CHROMIUM(III)-HEXOSE COMPLEXES AND THEIR IN-VITRO INTERACTION WITH DNA
Authors: RAO, CP
KAIWAR, SP
RAGHAVAN, MSS
Keywords: amino-acid
d-glucose
chromium(vi)
reduction
chromate
ions
derivatives
cations
binding
cells
Issue Date: 1994
Publisher: PERGAMON-ELSEVIER SCIENCE LTD
Citation: POLYHEDRON, 13(12), 1895-1906
Abstract: Saccharide complexes of Cr(III) were synthesized via chromate reduction. Hexose monosaccharides such as D-glucose, D-fructose, D-galactoSe, D-mannose and L-sorbose and some acid derivatives, such as D-galacturonic acid and D-gluconic acid, were used. The final Cr(III) products were isolated, purified and characterized by various analytical, spectroscopic, magnetic and electrochemical methods. All the products reported here are shown to be dinuclear in nature. The inherent stability and robust nature of these complexes is demonstrated and they are shown to affect the pSV2neo plasmid (DNA) structure in gel electrophoretic experiments.
URI: http://dx.doi.org/10.1016/0277-5387(94)80013-8
http://dspace.library.iitb.ac.in/xmlui/handle/10054/11503
http://hdl.handle.net/10054/11503
ISSN: 0277-5387
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