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|Title: ||Synthesis of highly functionalized phenylalanine derivatives via cross-enyne metathesis reactions|
|Authors: ||KOTHA, S|
|Keywords: ||amino-acid derivatives|
|Issue Date: ||2002|
|Publisher: ||PERGAMON-ELSEVIER SCIENCE LTD|
|Citation: ||TETRAHEDRON, 58(45), 9203-9208|
|Abstract: ||A new method for the synthesis of constrained phenylalanine derivatives is described. In this regard, the simple synthesis of acyclic diene building blocks embodying an alpha-amino acid moiety has been achieved. The diene building blocks have been prepared by cross enyne-metathesis reaction as a key step. The Diels-Alder reaction of the dienes with a dienophile such as dimethyl acetylenedicarboxilate (DMAD) followed by oxidation of the resulting cycloadduct gave highly substituted phenylalanine derivatives. (C) 2002 . .|
|Appears in Collections:||Article|
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