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|Title: ||Studies towards the synthesis of FCRR toxin: an expeditious entry into 7-5-6 ring systems via [5+2] oxidopyrylium-alkene cycloaddition|
|Authors: ||KRISHNA, UM|
|Issue Date: ||2004|
|Publisher: ||PERGAMON-ELSEVIER SCIENCE LTD|
|Citation: ||TETRAHEDRON LETTERS, 45(2), 257-259|
|Abstract: ||Synthetic studies towards the diterpene natural product FCRR toxin have been undertaken. Ail intermolecular [5+2] oxidopyrylium-alkene cycloaddition reaction was employed to construct the 7-5-6 tricyclic framework. The reaction proceeded with very high regio- and stereoselectivity and the bridging ether was reductively cleaved to unmask the carbocycle. (C) 2003|
|Appears in Collections:||Article|
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