DSpace
 

DSpace at IIT Bombay >
IITB Publications >
Article >

Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/11381

Title: STUDIES IN ALKYLATION OF 3-METHYL-3-SULFOLENE AND THERMOLYSIS OF RESULTING 2-ALKYL-3-SULFOLENES - CONVENIENT SYNTHESIS OF 1,2-DISUBSTITUTED-1,3-DIENES
Authors: DESAI, SR
GORE, VK
MAYELVAGANAN, T
PADMAKUMAR, R
BHAT, SV
Keywords: stereoselective synthesis
Issue Date: 1992
Publisher: PERGAMON-ELSEVIER SCIENCE LTD
Citation: TETRAHEDRON, 48(3), 481-490
Abstract: Various 1,2-disubstituted-1,3-dienes have been synthesised through the alkylation of 3-methyl-3-sulfolene (1) followed by thermolysis of the resulting 2-alkyl-3-methyl-3-sulfolene (3,7). The alkylations with bulky iodides, particularly, containing ethylene ketal or phenyl sulfide moiety yield considerable amounts of rearranged 2-alkyl-3-methyl-2-sulfolene (4). The sulfolenes 3,4 & 7 have been desulfonylated under mild conditions to yield corresponding 1,3-dienes.
URI: http://dx.doi.org/10.1016/S0040-4020(01)89010-4
http://dspace.library.iitb.ac.in/xmlui/handle/10054/11381
http://hdl.handle.net/10054/11381
ISSN: 0040-4020
Appears in Collections:Article

Files in This Item:

There are no files associated with this item.

View Statistics

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

 

Valid XHTML 1.0! DSpace Software Copyright © 2002-2010  Duraspace - Feedback