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|Title: ||Selective reduction of alkenes, alpha,beta-unsaturated carbonyl compounds, nitroarenes, nitroso compounds, N,N-hydrogenolysis of azo and hydrazo functions as well as simultaneous hydrodehalogenation and reduction of substituted aryl halides over PdMCM-41 catalyst under transfer hydrogen conditions|
|Authors: ||SELVAM, P|
|Keywords: ||aluminophosphate molecular-sieves|
hexagonal mesoporous aluminophosphates
|Issue Date: ||2004|
|Publisher: ||PERGAMON-ELSEVIER SCIENCE LTD|
|Citation: ||TETRAHEDRON LETTERS, 45(15), 3071-3075|
|Abstract: ||Chemoselective reductions of alkenes, alpha,beta-unsaturated carbonyl compounds, nitro and nitroso compounds, N,N-hydrogenolysis of azo and hydrazo functions as well as simultaneous reduction and hydrodehalogenation of substituted aryl halides, including bulkier substrates, were achieved by catalytic transfer hydrogenation (CTH) using mesoporous PdMCM-41 catalyst. The yields were practically unaffected upon recycling of the catalyst. Further, the CTH process is accomplished without affecting the reduction of any other reducible functional group. (C) 2004|
|Appears in Collections:||Article|
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