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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/11285

Title: Selective reduction of alkenes, alpha,beta-unsaturated carbonyl compounds, nitroarenes, nitroso compounds, N,N-hydrogenolysis of azo and hydrazo functions as well as simultaneous hydrodehalogenation and reduction of substituted aryl halides over PdMCM-41 catalyst under transfer hydrogen conditions
Authors: SELVAM, P
SONAVANE, SU
MOHAPATRA, SK
JAYARAM, RV
Keywords: aluminophosphate molecular-sieves
hexagonal mesoporous aluminophosphates
heterogeneous catalysts
unsaturated-ketones
transition-metal
room-temperature
oxidation
alcohols
dehalogenation
(cr)mcm-41
Issue Date: 2004
Publisher: PERGAMON-ELSEVIER SCIENCE LTD
Citation: TETRAHEDRON LETTERS, 45(15), 3071-3075
Abstract: Chemoselective reductions of alkenes, alpha,beta-unsaturated carbonyl compounds, nitro and nitroso compounds, N,N-hydrogenolysis of azo and hydrazo functions as well as simultaneous reduction and hydrodehalogenation of substituted aryl halides, including bulkier substrates, were achieved by catalytic transfer hydrogenation (CTH) using mesoporous PdMCM-41 catalyst. The yields were practically unaffected upon recycling of the catalyst. Further, the CTH process is accomplished without affecting the reduction of any other reducible functional group. (C) 2004
URI: http://dx.doi.org/10.1016/j.tetlet.2004.02.098
http://dspace.library.iitb.ac.in/xmlui/handle/10054/11285
http://hdl.handle.net/10054/11285
ISSN: 0040-4039
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