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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/11284

Title: Selective recognition of Zn(2+) by salicylaldimine appended triazole-linked di-derivatives of calix[4]arene by enhanced fluorescence emission in aqueous-organic solutions: role of terminal -CH(2)OH moieties in conjunction with the imine in recognition
Authors: PATHAK, RK
IBRAHIM, SM
RAO, CP
Keywords: transition-metal ions
intracellular zinc
biological-systems
electron-transfer
in-vivo
sensor
design
zn(ii)
probe
chemosensor
Issue Date: 2009
Publisher: PERGAMON-ELSEVIER SCIENCE LTD
Citation: TETRAHEDRON LETTERS, 50(23), 2730-2734
Abstract: A series of lower rim 1,3-di-derivatives possessing Schiff's base cores were synthesized using triazole unit as linker moiety by further introducing butyl (L(2)), one -CH(2)CH (L(3)) and two -CH(2)OH (L(4))-containing moieties, respectively, in order to bring additional support for ion binding. Based on fluorescence and absorption spectroscopies it has been shown that Zn(2+) Could be selectively recognized by the Schiff's base core and not by the triazole core among the ten metal ions studied both in methanol and in aqueous Solutions of methanol and acetonitrile, wherein the -CH(2)OH moieties augment the fluorescence response by providing additional coordinations to the Zn(2+). Thus L(4) exhibited a fluorescence enhancement of similar to 65, similar to 48 and similar to 25-fold in methanol. aqueous Solutions of methanol and acetonitrile. with minimum detection limits of 174. 3 13 and 320 ppb, respectively. Both the excitation and emission wavelengths fall in visible region. (C) 2009
URI: http://dx.doi.org/10.1016/j.tetlet.2009.03.126
http://dspace.library.iitb.ac.in/xmlui/handle/10054/11284
http://hdl.handle.net/10054/11284
ISSN: 0040-4039
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