DSpace
 

DSpace at IIT Bombay >
IITB Publications >
Article >

Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/11216

Title: RCM/PCC oxidation strategy for synthesis of functionalized cyclic alpha,beta-unsaturated lactones: synthesis of (+)-triacetoxygoniotriol and its diastereomers
Authors: SRIKANTH, GSC
KRISHNA, UM
TRIVEDI, GK
CANNON, JF
Keywords: goniothalamus-giganteus annonaceae
styryl-lactones
pyridinium chlorochromate
(+)-goniofufurone
(+)-goniotriol
8-acetylgoniotriol
(+)-goniopypyrone
(+)-altholactone
goniofufurone
ring
Issue Date: 2006
Publisher: PERGAMON-ELSEVIER SCIENCE LTD
Citation: TETRAHEDRON, 62(48), 11165-11171
Abstract: A novel methodology leading to the synthesis of (+)-triacetoxygoniotriol 2 from D-glucose is described. Construction of the core six-membered alpha, beta-unsaturated lactone moiety involved ring closing metathesis (RCM) followed by a PCC oxidation. Later exploiting the pseudo-symmetry of D-glucose three other diastereomers of triacetoxygoniotriol were synthesized using the developed methodology. (c) 2006
URI: http://dx.doi.org/10.1016/j.tet.2006.09.016
http://dspace.library.iitb.ac.in/xmlui/handle/10054/11216
http://hdl.handle.net/10054/11216
ISSN: 0040-4020
Appears in Collections:Article

Files in This Item:

There are no files associated with this item.

View Statistics

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

 

Valid XHTML 1.0! DSpace Software Copyright © 2002-2010  Duraspace - Feedback