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|Title: ||RCM/PCC oxidation strategy for synthesis of functionalized cyclic alpha,beta-unsaturated lactones: synthesis of (+)-triacetoxygoniotriol and its diastereomers|
|Authors: ||SRIKANTH, GSC|
|Keywords: ||goniothalamus-giganteus annonaceae|
|Issue Date: ||2006|
|Publisher: ||PERGAMON-ELSEVIER SCIENCE LTD|
|Citation: ||TETRAHEDRON, 62(48), 11165-11171|
|Abstract: ||A novel methodology leading to the synthesis of (+)-triacetoxygoniotriol 2 from D-glucose is described. Construction of the core six-membered alpha, beta-unsaturated lactone moiety involved ring closing metathesis (RCM) followed by a PCC oxidation. Later exploiting the pseudo-symmetry of D-glucose three other diastereomers of triacetoxygoniotriol were synthesized using the developed methodology. (c) 2006|
|Appears in Collections:||Article|
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