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| Title: | OXOVANADIUM(V) SCHIFF-BASE COMPLEXES OF TRISHYDROXYMETHYLAMINOMETHANE WITH SALICYLALDEHYDE AND ITS DERIVATIVES - SYNTHESIS, CHARACTERIZATION AND REDOX REACTIVITY |
| Authors: | ASGEDOM, G
SREEDHARA, A
RAO, CP |
| Keywords: | ascophyllum-nodosum
vanadium
spectroscopy
chemistry
model |
| Issue Date: | 1995 |
| Publisher: | PERGAMON-ELSEVIER SCIENCE LTD |
| Citation: | POLYHEDRON, 14(13-14), 1873-1879 |
| Abstract: | Five vanadium complexes possessing the VO3+ motif with NO4 coordination have been synthesized and characterized by H-1 and C-13 NMR, UV-Vis, FTIR and cyclic voltammetry. These complexes favour trigonal bipyramidal geometry. In DMF solution, complexes 1 and 5 have shown reversible redox behaviour in the presence of L-ascorbic acid or L-cysteine ethyl ester in air as monitored by electronic absorption and EPR studies. |
| URI: | http://dx.doi.org/10.1016/0277-5387(94)00461-M
http://dspace.library.iitb.ac.in/xmlui/handle/10054/11150
http://hdl.handle.net/10054/11150 |
| ISSN: | 0277-5387 |
| Appears in Collections: | Article
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