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|Title: ||OXOVANADIUM(V) SCHIFF-BASE COMPLEXES OF TRISHYDROXYMETHYLAMINOMETHANE WITH SALICYLALDEHYDE AND ITS DERIVATIVES - SYNTHESIS, CHARACTERIZATION AND REDOX REACTIVITY|
|Authors: ||ASGEDOM, G|
|Issue Date: ||1995|
|Publisher: ||PERGAMON-ELSEVIER SCIENCE LTD|
|Citation: ||POLYHEDRON, 14(13-14), 1873-1879|
|Abstract: ||Five vanadium complexes possessing the VO3+ motif with NO4 coordination have been synthesized and characterized by H-1 and C-13 NMR, UV-Vis, FTIR and cyclic voltammetry. These complexes favour trigonal bipyramidal geometry. In DMF solution, complexes 1 and 5 have shown reversible redox behaviour in the presence of L-ascorbic acid or L-cysteine ethyl ester in air as monitored by electronic absorption and EPR studies.|
|Appears in Collections:||Article|
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