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| Title: | Cycloaddition of annulated cyclohexa-2,4-dienones and novel reduction of halogen at bridgehead: an expedient route to tetracyclo[6.5.2.0(2,7).0(9,13)]pentadec-2(7),11-dien-14-one and framework of conidiogenol and conidiogenone |
| Authors: | SINGH, V
SINGH, RB
MOBIN, SM |
| Keywords: | lycopodium alkaloids
organic-synthesis
(+)-magellaninone
(-)-magellanine
magellanine
diterpenes
phenols |
| Issue Date: | 2009 |
| Publisher: | PERGAMON-ELSEVIER SCIENCE LTD |
| Citation: | TETRAHEDRON, 65(38), 7969-7974 |
| Abstract: | An expedient route to tetracyclo[6.5.2.0(2,7).0(9,13)]pentadec-2(7),11-dien-14-one and tetracyclic framework of conidiogenol have been reported. Cycloaddition of annulated cyclohexa-2,4-dienone with cyclopentadiene, photochemical oxa-di-pi-methane reaction and a highly unusual dehalogenation of bridgehead halogen are the key features of our methodology. (C) 2009 |
| URI: | http://dx.doi.org/10.1016/j.tet.2009.07.051
http://dspace.library.iitb.ac.in/xmlui/handle/10054/10688
http://hdl.handle.net/10054/10688 |
| ISSN: | 0040-4020 |
| Appears in Collections: | Article
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