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|Title: ||Cycloaddition of annulated cyclohexa-2,4-dienones and novel reduction of halogen at bridgehead: an expedient route to tetracyclo[220.127.116.11(2,7).0(9,13)]pentadec-2(7),11-dien-14-one and framework of conidiogenol and conidiogenone|
|Authors: ||SINGH, V|
|Keywords: ||lycopodium alkaloids|
|Issue Date: ||2009|
|Publisher: ||PERGAMON-ELSEVIER SCIENCE LTD|
|Citation: ||TETRAHEDRON, 65(38), 7969-7974|
|Abstract: ||An expedient route to tetracyclo[18.104.22.168(2,7).0(9,13)]pentadec-2(7),11-dien-14-one and tetracyclic framework of conidiogenol have been reported. Cycloaddition of annulated cyclohexa-2,4-dienone with cyclopentadiene, photochemical oxa-di-pi-methane reaction and a highly unusual dehalogenation of bridgehead halogen are the key features of our methodology. (C) 2009|
|Appears in Collections:||Article|
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