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|Title: ||CONVENIENT SYNTHESIS OF DECALIN SYSTEMS OF BIOACTIVE TERPENOIDS|
|Authors: ||GORE, VK|
|Keywords: ||diels-alder reactions|
|Issue Date: ||1993|
|Publisher: ||PERGAMON-ELSEVIER SCIENCE LTD|
|Citation: ||TETRAHEDRON, 49(13), 2767-2782|
|Abstract: ||New analogues of bioactive terpenoids, forskolin, nimbolide, isozonarol and ambrox have been synthesized using general Diels-Alder reaction of 2-formyl-4,4-dimethyl-cyclohexa-2,5-dienone (7) with 1,2-disubstituted-1,3-dienes (8a-k) which yielded endo- & exo-adducts. The deformylation, epimerisation, angular methylation, reduction and oxidation studies on these adducts have been reported.|
|Appears in Collections:||Article|
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