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| Title: | Transition metal (Group 6, Ru and Group 10) derivatives of aminophosphines, Ph2PN(H)R (R=Ph, C6H11) |
| Authors: | SRINIVASAN, PRASHANT
BALAKRISHNA, MS
MAGUE, JOEL T |
| Keywords: | derivatives
transition metals
x-ray crystallography
synthesis |
| Issue Date: | 2003 |
| Publisher: | Elsevier |
| Citation: | Journal of Organometallic Chemistry 679(1), 116-124 |
| Abstract: | The reactions of aminophosphines with Group 6 metal carbonyls afford both mono-substituted and disubstituted complexes. The reaction of Ph2PN(H)C6H11 with molybdenum tetracarbonyl derivative gives a mixture of cis and trans-isomers. The reaction of Ph2PN(H)Ph with Pd(COD)Cl2 leads to the P-N bond cleavage to give chloro bridged dimer, [Pd(PPh2O)(PPh2OH)(μ-Cl)]2, whereas with Pt(COD)Cl2, disubstituted cis-[PtCl2{PPh2N(H)R}2]2 was obtained. The reaction of Ph2PN(H)C6H11 with RuCl2(DMSO)4 or RuCl2(PPh3)3 leads to the formation of ionic complex, [RuCl{Ph2PN(H)C6H11}3]Cl. |
| URI: | http://dx.doi.org/10.1016/S0022-328X(03)00543-6
http://hdl.handle.net/10054/1041
http://dspace.library.iitb.ac.in/xmlui/handle/10054/1041 |
| ISSN: | 0022-328X |
| Appears in Collections: | Article
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