Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/xmlui/handle/10054/1036
Title: Silver(I) complexes of bis[2-(diphenylphosphino)phenyl] ether
Authors: BALAKRISHNA, MS
RAMALINGAM, VENKATESWARAN
SHAIKH, MOBIN M
Keywords: X-Ray Crystallography
Instrumentation
Synthesis
Crystal Structure
Issue Date: 2008
Publisher: Elsevier
Citation: Polyhedron 27(3), 899-904
Abstract: The reaction of AgOTf in dichloromethane with bis(2-(diphenylphosphino)phenyl) ether (DPEphos) in an equimolar ratio afforded a dinuclear complex [Ag2(κ2-P,P′-DPEphos)2(μ-OTf)2] (1), whereas the similar reaction in a 1:2 molar ratio resulted in the formation of a bis-chelating complex [Ag(κ2-P,P′-DPEphos)2][OTf] (2). The silver(I) complex 1 was obtained as a dimer, in which two silver atoms are bridged by two triflate groups to form three adjacent eight-membered spirocyclic rings. The mixed-ligand complex [Ag(κ2-P,P′-DPEphos)(2,2′-bpy)][OTf] (3) was obtained in the reaction of 1 in dichloromethane with 2,2′-bipyridine. The crystal structures of complexes 1–3 were determined by single crystal X-ray analyses.
URI: http://dx.doi.org/10.1016/j.poly.2007.11.019
http://hdl.handle.net/10054/1036
http://dspace.library.iitb.ac.in/xmlui/handle/10054/1036
ISSN: 0277-5387
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