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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/10245

Title: Mono- and di-nuclear Cu(II) complexes of p-tert-butyl-calix[4]arene-1,3-diacid derivative: A comparative study of their characterization and catecholase mimetic activity
Authors: ALI, A
SALUNKE-GAWALI, S
RAO, CP
LINARES, J
Keywords: copper(ii) complexes
crystal-structure
lower rim
pendants
oxidases
Issue Date: 2006
Publisher: NATL INST SCIENCE COMMUNICATION
Citation: INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 45(4), 853-857
Abstract: Reaction of copper(II) perchlorate with p-tert-butyl-calix[4]arene-1,3-diacid gives mono-nuclear complex in acetonitrile and dinuclear complex in methanol which have been isolated as their pyridine bound adducts. The dinuclear complex exhibits different characteristics in its EPR and magnetic studies. The reactivity studies clearly indicate that the dinuclear complex has higher catecholase mimetic activity over its mononuclear counterpart owing to its coordination favourability.
URI: http://dspace.library.iitb.ac.in/xmlui/handle/10054/10245
http://hdl.handle.net/10054/10245
ISSN: 0376-4710
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