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| Title: | Mono- and di-substituted urea derivatives of cyclodiphosphazane: [ClP(μ-NtBu)2PN(Me)CON(H)Me] and [Me(H)NCON(Me)P(μ-NtBu)]2 |
| Authors: | SURESH, D
BALAKRISHNA, MS
MAGUE, JOEL T |
| Keywords: | intermolecular forces
derivatives
molecular structure
x-ray diffraction |
| Issue Date: | 2007 |
| Publisher: | Elsevier |
| Citation: | Tetrahedron Letters 48(13), 2283-2285 |
| Abstract: | The reaction of cis-[ClP(μ-NtBu)]2 with N,N′-dimethylurea leads to the formation of both mono- and di-substituted derivatives [ClP(μ-NtBu)2P(NMeCON(H)Me)] and [(μ-NtBu)P(NMeCON(H)Me)]2, instead of monomeric, dimeric or higher oligomeric macrocycles. The structure of [ClP(μ-NtBu)2P(NMeCON(H)Me)] shows rare non-bonded P...Cl and intermolecular hydrogen bonding interactions leading to a 2D-sheet like structure. |
| URI: | http://dx.doi.org/10.1016/j.tetlet.2007.01.164
http://hdl.handle.net/10054/1021
http://dspace.library.iitb.ac.in/xmlui/handle/10054/1021 |
| ISSN: | 0040-4039 |
| Appears in Collections: | Article
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