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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/1021

Title: Mono- and di-substituted urea derivatives of cyclodiphosphazane: [ClP(μ-NtBu)2PN(Me)CON(H)Me] and [Me(H)NCON(Me)P(μ-NtBu)]2
Authors: SURESH, D
BALAKRISHNA, MS
MAGUE, JOEL T
Keywords: intermolecular forces
derivatives
molecular structure
x-ray diffraction
Issue Date: 2007
Publisher: Elsevier
Citation: Tetrahedron Letters 48(13), 2283-2285
Abstract: The reaction of cis-[ClP(μ-NtBu)]2 with N,N′-dimethylurea leads to the formation of both mono- and di-substituted derivatives [ClP(μ-NtBu)2P(NMeCON(H)Me)] and [(μ-NtBu)P(NMeCON(H)Me)]2, instead of monomeric, dimeric or higher oligomeric macrocycles. The structure of [ClP(μ-NtBu)2P(NMeCON(H)Me)] shows rare non-bonded P...Cl and intermolecular hydrogen bonding interactions leading to a 2D-sheet like structure.
URI: http://dx.doi.org/10.1016/j.tetlet.2007.01.164
http://hdl.handle.net/10054/1021
http://dspace.library.iitb.ac.in/xmlui/handle/10054/1021
ISSN: 0040-4039
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