Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/xmlui/handle/10054/1018
Title: Synthesis, spectroscopic study and X-ray crystal structure of unsymmetrical bis(phosphine)-platinum complex, [PtCl2{η2-Ph2POCH2CH2N(CH3)PPh2]
Authors: BALAKRISHNA, MS
MCDONALD, ROBERT
Keywords: Spectroscopic Analysis
X-Ray Crystallography
Experimental
Synthesis
Issue Date: 2002
Publisher: Elsevier
Citation: Inorganic Chemistry Communications 5(10), 782-786
Abstract: The bis(phosphine), Ph2POCH2CH2N(CH3)PPh2(1) reacts with [Pt(COD)Cl2] to give seven-membered cis-chelated complex 2. The complex was characterized by elemental analysis, IR, and NMR spectroscopic methods of which the 31P{1H} NMR data is very informative and allows the direct measure of the P–P coupling through metal centers otherwise can not be seen in the free ligand as the two phosphorus centers are five-bonds apart. The structure of the platinum(II) complex was determined by X-ray crystallography.
URI: http://dx.doi.org/10.1016/S1387-7003(02)00558-0
http://hdl.handle.net/10054/1018
http://dspace.library.iitb.ac.in/xmlui/handle/10054/1018
ISSN: 1387-7003
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