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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/1017

Title: First examples of methylene insertion into the phosphorus(III)–nitrogen bond
Authors: SRINIVASAN, PRIYA
BALAKRISHNA, MS
MAGUE, JOEL T
Keywords: insertion
phosphinoamine
phosphine oxide
paraformaldehyde
Issue Date: 2001
Publisher: Elsevier
Citation: Inorganic Chemistry Communications 4(8), 437-440
Abstract: The reaction of N-substituted phosphinous amides with paraformaldehyde leads to methylene insertion into the P–N bond, followed by the oxidation of phosphorus from P(III) to P(V) state. The product, Ph2P(O)CH2NHPh was characterised by a single-crystal X-ray diffraction study. The reaction not only depends on the acidic proton on the nitrogen, but also on the oxidation state of phosphorus and it is considered to proceed through Staudinger–Wittig pathway.
URI: http://dx.doi.org/10.1016/S1387-7003(01)00222-2
http://hdl.handle.net/10054/1017
http://dspace.library.iitb.ac.in/xmlui/handle/10054/1017
ISSN: 1387-7003
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