DSpace
 

DSpace at IIT Bombay >
IITB Publications >
Article >

Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/10138

Title: Mixed-chalcogenide double-butterfly complex [{(CO)(6)Fe2SSe}(2){mu-C(H)-C(H)}]
Authors: PANNEERSELVAM, K
LU, TH
TUNG, SF
DASH, AK
MATHUR, P
Keywords: acetylenic bond reduction
structural characterization
clusters
fe2(co)6(mu-se2)
phenylacetylene
iron
Issue Date: 2000
Publisher: MUNKSGAARD INT PUBL LTD
Citation: ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 56(), 438-439
Abstract: Bubbling acetylene gas slowly through a methanol solution of [(CO)(6)Fe-2{mu-SSe}] containing sodium acetate for 48 h at room temperature yields the double-butterfly complex mu-[ethane-1,1,2,2-tetra(selenido/sulfido)]bis[hexacarbonyldiiron(Fe - Fe)], [Fe-4(C2H2S2Se2)(CO)(12)]. The molecular structure was established by single-crystal X-ray diffraction techniques. The structure consists of two Fe2SSe butterfly units linked to each other through a bridging HC-CH group. The molecule has twofold symmetry and the two Fe atoms have distorted octahedral geometries.
URI: http://dx.doi.org/10.1107/S0108768100001038
http://dspace.library.iitb.ac.in/xmlui/handle/10054/10138
http://hdl.handle.net/10054/10138
ISSN: 0108-2701
Appears in Collections:Article

Files in This Item:

There are no files associated with this item.

View Statistics

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

 

Valid XHTML 1.0! DSpace Software Copyright © 2002-2010  Duraspace - Feedback