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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/1009

Title: Silicon based phosphines with P–Si–P, P–C–Si–C–P and P–O–Si–O–P linkages and their coordination chemistry and catalytic applications
Authors: BALAKRISHNA, MS
CHANDRASEKARAN, P
GEORGE, PP
Keywords: single crystals
x-ray diffraction
spectroscopic analysis
catalysis
Issue Date: 2003
Publisher: Elsevier
Citation: Coordination Chemistry Reviews 241(1-2), 87-117
Abstract: The synthesis and coordination chemistry of bis- and tris(phosphines) with P–Si–P, P–O–Si–O–P and P–C–Si–C–P linkages is reviewed. The catalytic reactions involving organometallic complexes of silylphosphines are presented. The silylbis- and tris(phosphines) show remarkable versatility in their coordination behavior with transition metals. The improved solubility of these ligands and their complexes facilitated spectroscopic studies to compliment the structural information obtained via single crystal X-ray diffraction studies. The syntheses and reactivity of other related acyclic and cyclic systems with P–N–Si–N–P and P–aryl–Si-aryl–P linkages are also briefly described.
URI: http://dx.doi.org/10.1016/S0010-8545(03)00018-3
http://hdl.handle.net/10054/1009
http://dspace.library.iitb.ac.in/xmlui/handle/10054/1009
ISSN: 0010-8545
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