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| Title: | Synthesis and thermochemical study of ligand substitution reactions of aminobis(phosphines), Ph2P(R)NPPh2, with [Me2Pt(COD)] |
| Authors: | BALAKRISHNA, MS
PRIYA, SRINIVASAN
SOMMER, WILLIAM
NOLAN, STEVEN P |
| Keywords: | substitution reactions
thermochemistry
enthalpy
synthesis |
| Issue Date: | 2005 |
| Publisher: | Elsevier |
| Citation: | Inorganica Chimica Acta 358(9), 2817-2820 |
| Abstract: | The reactions of aminobis(phosphines), Ph2PN(R)PPh2 (R = H, Me, Et, nPr, nBu, Ph), with Me2Pt(COD) led to the formation of four-membered metallacycles in good yield. The enthalpies of the ligand substitution reactions are measured by the anaerobic solution calorimetry in THF at 30 °C. |
| URI: | http://dx.doi.org/10.1016/j.ica.2005.03.021
http://hdl.handle.net/10054/1007
http://dspace.library.iitb.ac.in/xmlui/handle/10054/1007 |
| ISSN: | 0020-1693 |
| Appears in Collections: | Article
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