DSpace
 

DSpace at IIT Bombay >
IITB Publications >
Article >

Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/10054/1005

Title: Suzuki cross-coupling reactions catalyzed by palladium complex of an inexpensive phosphinite, 2-diphenylphosphinoxynaphthyl
Authors: PUNJI, BENUDHAR
GANESAMOORTHY, C
BALAKRISHNA, MS
Keywords: chemical reactions
reaction kinetics
palladium
thermal effects
Issue Date: 2006
Publisher: Elsevier
Citation: Journal of Molecular Catalysis A: Chemical 259(1-2), 78-83
Abstract: A facile and less expensive monophosphinite ligand 2-(diphenylphosphinoxy)-naphthyl, C10H7OPPh2(1) has been synthesized from the reaction of β-naphthol with chlorodiphenylphosphine. The mixture of Pd(OAc)2 and 1 catalyzes the Suzuki cross-coupling of a variety of aryl halides with aryl boronic acids at room temperature or at 60°C, giving generally high yields even under low catalytic loads. The effect of solvent, base and catalyst loading on the coupling reaction of aryl halide with arylboronic acid is also described.
URI: http://dx.doi.org/10.1016/j.molcata.2006.05.067
http://hdl.handle.net/10054/1005
http://dspace.library.iitb.ac.in/xmlui/handle/10054/1005
ISSN: 1381-1169
Appears in Collections:Article

Files in This Item:

File Description SizeFormat
5258.pdf365.95 kBAdobe PDFView/Open
View Statistics

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

 

Valid XHTML 1.0! DSpace Software Copyright © 2002-2010  Duraspace - Feedback