DSpace
 

DSpace at IIT Bombay >
IITB Publications >
Note >

Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/100/690

Title: Acetylenic bond reduction on fe2(co)6(mu-se2) and synthesis of the double-butterfly complex [((co)6fe2(mu-se)2)2c(ph)-c(h)]
Authors: MATHUR, P
HOSSAIN, M
Issue Date: 1993
Publisher: AMER CHEMICAL SOC
Citation: ORGANOMETALLICS,12(6)2398-2400
Abstract: Room-temperature reaction Of [Fe2(CO)6{mu-SeC(Ph)=C(H)Se}] (1) with Fe2(CO)6(mu-Se2) gives the double-butterfly complex [{(CO)6Fe2(mu-Se)2}2C(Ph)-C-(H)] (2). The structures of 1 and 2 have been determined by single-crystal X-ray diffraction studies 1: P2(1)/a, a = 14.561 (1) angstrom, b = 6.666(l) angstrom c = 17.475(1) angstrom, beta = 91.22(1)-degrees, V = 1695.8(4) angstrom3, z = 4, R = 3.98 %, and R(w) = 4.59 %. 2: monoclinic, P1BAR, a = 8.913(l) angstrom, b = 9.115(1) angstrom, c = 17.556-(1) angstrom, a = 74.97(l)-degrees, beta = 84.96(l)-degrees, gamma = 86.09(1)-degrees, V = 1367.5(4) angstrom3, Z = 2, R = 4.69%, and R(w) = 4.89%. Structural analysis shows the systematic reduction of the acetylenic C=C bond on the Fe2Se2 frameworks of 1 and 2.
URI: http://dx.doi.org/10.1021/om00030a063
http://dspace.library.iitb.ac.in/xmlui/handle/10054/13106
http://hdl.handle.net/100/690
ISSN: 0276-7333
Appears in Collections:Note

Files in This Item:

There are no files associated with this item.

View Statistics

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

 

Valid XHTML 1.0! DSpace Software Copyright © 2002-2010  Duraspace - Feedback