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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/100/689

Title: Selenium-bridged clusters - synthesis and structural characterization of cp2mo2fe2(mu(4)-se)(mu(3)-se)2(co)6
Authors: MATHUR, P
HOSSAIN, MM
RHEINGOLD, AL
Issue Date: 1993
Publisher: AMER CHEMICAL SOC
Citation: ORGANOMETALLICS,12(12)5029-5031
Abstract: Thermolysis of Fe2(CO)6{mu-SeC(Ph)=C(H)Se} (1) and Cp2Mo2(CO)6 (2) yields the new cluster Cp2Mo2Fe2(mu4-Se)(mu3-Se)2(CO)6 (3) and Cp2Mo2(CO)4(PhCCH) (4). Structural characterization of 3 shows an unusual mu4-Se ligand bridging the two wing-tip Fe atoms and the two hinge Mo atoms of the Mo2Fe2 butterfly-tetrahedron core.
URI: http://dx.doi.org/10.1021/om00036a054
http://dspace.library.iitb.ac.in/xmlui/handle/10054/13105
http://hdl.handle.net/100/689
ISSN: 0276-7333
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