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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/100/658

Title: Functionalization of a diacetylene on the mixed-chalcogenide compound fe2(co)6(mu-ste) - structural characterization of (co)6fe2(mu-sc(c-equivalent-to-cch3)=c(h)te)
Authors: MATHUR, P
HOSSAIN, MM
DATTA, SN
KONDRU, RK
BHADBHADE, MM
Issue Date: 1994
Publisher: AMER CHEMICAL SOC
Citation: ORGANOMETALLICS,13(6)2532-2535
Abstract: The room-temperature reaction of the mixed-chalcogenide complex Fe2(CO)6(mu-STe) with the diacetylene CH3C=CC=CH forms the new compound (CO)6Fe2{mu-SC(C=CCH3)=C(H)Te}. The structure of (CO)6Fe2{mu-SC(C=CCH3)=C(H)Te} has been established by single-crystal X-ray diffraction methods: P1BAR, a = 6.587(2) angstrom, b = 10.689(3) angstrom, c = 11.067(3) angstrom, alpha = 92.74(2)-degrees, beta = 92.77(2)-degrees, gamma = 97.23(2)-degrees, V = 771(3) angstrom3, Z = 2, R = 5.6%, R(w) = 6.8%. Molecular orbital calculations have been performed on the four possible isomers of (CO)6Fe2{mu-SC(C=CCH3)=C(H)Te} which can be expected to form, and the formation of the experimentally found isomer has been rationalized.
URI: http://dx.doi.org/10.1021/om00018a059
http://dspace.library.iitb.ac.in/xmlui/handle/10054/13077
http://hdl.handle.net/100/658
ISSN: 0276-7333
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