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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/100/3101

Title: Heteroatom-directed aromatic lithiation: a versatile route to the synthesis of organochalcogen (se, te) compounds
Authors: MUGESH, G
SINGH, HB
Issue Date: 2002
Publisher: AMER CHEMICAL SOC
Citation: ACCOUNTS OF CHEMICAL RESEARCH,35(4)226-236
Abstract: Chiral and achiral organochalcogen compounds bearing a heteroatom in close proximity are easily accessible via the directed aromatic lithiation route. The lithium chalcogenolates prepared by the insertion of selenium or tellurium into the C-Li bond are used to synthesize various chalcogen compounds such as Se/Te, N donor ligands, dichalcogenides, monomeric metal chalcogenolates, and macrocycles. The differences in the stability and reactivity of the organochalcogen compounds derived from various substrates are described in terms of electronic and stereochemical properties of donor atoms.
URI: http://dx.doi.org/10.1021/ar010091k
http://dspace.library.iitb.ac.in/xmlui/handle/10054/13901
http://hdl.handle.net/100/3101
ISSN: 0001-4842
Appears in Collections:Review

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