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|Title:||Synthesis of novel quinone-amino acid hybrids via cross-enyne metathesis and diels-alder reaction as key steps|
|Keywords:||Quinone-Amino Acid Hybrids|
|Publisher:||WILEY-V C H VERLAG GMBH|
|Citation:||EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,(8)1244-1255|
|Abstract:||A "Building Block Approach" for the synthesis of various quinone-amino acid hybrids through ethylene cross-enyne metathesis and Diels-Alder reaction as key steps is described. A library of comformationally constrained quinone-based phenylalanine derivatives and dicarba analogs of cystine have been generated starting from a common precursor using Grubbs' catalysts. This methodology has also been extended for the synthesis of fullerene-based dicarba analogs of cystine. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007).|
|Appears in Collections:||Review|
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