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|Title: ||Synthesis of novel quinone-amino acid hybrids via cross-enyne metathesis and diels-alder reaction as key steps|
|Authors: ||KOTHA, S|
|Keywords: ||quinone-amino acid hybrids|
|Issue Date: ||2007|
|Publisher: ||WILEY-V C H VERLAG GMBH|
|Citation: ||EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,(8)1244-1255|
|Abstract: ||A "Building Block Approach" for the synthesis of various quinone-amino acid hybrids through ethylene cross-enyne metathesis and Diels-Alder reaction as key steps is described. A library of comformationally constrained quinone-based phenylalanine derivatives and dicarba analogs of cystine have been generated starting from a common precursor using Grubbs' catalysts. This methodology has also been extended for the synthesis of fullerene-based dicarba analogs of cystine. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007).|
|Appears in Collections:||Review|
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